Selectivity of cyano-Gilman cuprates: synthesis of 10-membered ring cyclophanes

Authors
Kabir, SMH Iyoda, M
Citation
Smh. Kabir et M. Iyoda, Selectivity of cyano-Gilman cuprates: synthesis of 10-membered ring cyclophanes, PHYS CHEM P, 2(23), 2000, pp. 2329-2330
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
2
Issue
23
Year of publication
2000
Pages
2329 - 2330
Database
ISI
SICI code
1463-9076(2000)2:23<2329:SOCCSO>2.0.ZU;2-8
Abstract
The oxidation of cyano-Gilman cuprates, derived from dibromodithienyl sulfi de, dibromodithienyldimethylsilane and dibromodithienylmethane, with molecu lar oxygen furnishes 10-membered ring cyclophanes selectively and an X-ray analysis of cyclophane 9 reveals that it possesses an anti conformation.