Anionic metal dicyanamide networks with paramagnetic counter-cations

Authors
Batten, SR Jensen, P Moubaraki, B Murray, KS
Citation
Sr. Batten et al., Anionic metal dicyanamide networks with paramagnetic counter-cations, PHYS CHEM P, 2(23), 2000, pp. 2331-2332
Citations number
26
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
2
Issue
23
Year of publication
2000
Pages
2331 - 2332
Database
ISI
SICI code
1463-9076(2000)2:23<2331:AMDNWP>2.0.ZU;2-X
Abstract
The M(bipy)(3)(2+) cations in the isomorphous structures of [M(bipy)(3)][M' (dca)(3)](2), [dca = dicyanamide, N(CN)(2)(-); M = Fe, M' = Mn 1, Fe 2 or M = Ni, M' = Mn 3] are contained within hexagonal windows of anionic 2D (6,3 ) M(dca)(3)(-) sheets; weak antiferromagnetic coupling is observed between metal centres within the anionic networks of all three compounds.