Temperature and solvent effects on enzyme stereoselectivity: inversion temperature in kinetic resolutions with lipases

Authors
Cainelli, G De Matteis, V Galletti, P Giacomini, D Orioli, P
Citation
G. Cainelli et al., Temperature and solvent effects on enzyme stereoselectivity: inversion temperature in kinetic resolutions with lipases, PHYS CHEM P, 2(23), 2000, pp. 2351-2352
Citations number
29
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
2
Issue
23
Year of publication
2000
Pages
2351 - 2352
Database
ISI
SICI code
1463-9076(2000)2:23<2351:TASEOE>2.0.ZU;2-N
Abstract
Eyring plots of lnE vs. 1/T show inversion temperature in kinetic resolutio n by lipases, demonstrating that clustering effects in the substrate solvat ion manage the enzymatic selectivity.