First catalytic dihydroamination of a phosphaalkyne. Crystal and molecularstructure of trans-[PdCl2{P((PrNH)-N-i)(2)CH2But}(2)]

Authors
Cloke, FGN Hitchcock, PB Nixon, JF Wilson, DJ
Citation
Fgn. Cloke et al., First catalytic dihydroamination of a phosphaalkyne. Crystal and molecularstructure of trans-[PdCl2{P((PrNH)-N-i)(2)CH2But}(2)], PHYS CHEM P, 2(23), 2000, pp. 2387-2388
Citations number
22
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
2
Issue
23
Year of publication
2000
Pages
2387 - 2388
Database
ISI
SICI code
1463-9076(2000)2:23<2387:FCDOAP>2.0.ZU;2-J
Abstract
Treatment of a dichloromethane solution of (BuCP)-C-t, containing a catalyt ic amount of TiCl4, with an excess of the primary amines RNH2 (R = Pr-i, Bu -t) quantitatively affords the corresponding bis-dialkylaminophosphine P((B uNH)-N-t)(2)- CH2But. P((PrNH)-N-i)(2)CH2But is structurally characterised by a single crystal X-ray diffraction study of its bis-trans-PdCl2 complex.