Pb2+ complex combinations with Criptand [2,2]

Authors
Mohora, T Luca, C
Citation
T. Mohora et C. Luca, Pb2+ complex combinations with Criptand [2,2], REV CHIM, 51(8), 2000, pp. 559-565
Citations number
14
Categorie Soggetti
Chemical Engineering
Journal title
REVISTA DE CHIMIE
ISSN journal
00347752 → ACNP
Volume
51
Issue
8
Year of publication
2000
Pages
559 - 565
Database
ISI
SICI code
0034-7752(200008)51:8<559:PCCWC[>2.0.ZU;2-4
Abstract
The Pb2+ complexes with macrocyclic ligand 1,7,10,16. Tetraoxa 4, 13 diazac iclooctadecan (Criptand [2.2])] were studied The stability-constants of the studied complexes were determined by potentiometric methods which showed t hat there is two complexes Pb2+-complexes [2,2], 1:1 and 1:2 (metal-ligand ratio), that is formed. The stability of these complexes showed that cripta nd [2,2] can be used as analitic reactiv for Pb2+ potentiometric determinat ion.