Ov. Mikhailov et Ai. Khamitova, Template synthesis in the Ni(II)-dithiooxamide-glyoxal ternary system in gelatin-immobilized matrices, RUSS J C CH, 26(11), 2000, pp. 804-808
Complexation in nickel(II) hexacyanoferrate(II) gelatin-immobilized matrice
s was studied in the Ni(II)-dithiooxamide-glyoxal system, It was shown that
template synthesis in this system affords a coordination 1:1 Ni(II) compou
nd with a tetradentate N,N,S,S-donor ligand, namely, 2,7-dithio-3,6-diazaoc
tadiene-3,5-dithioamide-1,8. The scheme of this synthesis is presented.