Crystal structure of oxoboratogermanate NdxSmyEuzGd4-x-y-zGe2B6O34

Citation
Kk. Palkina et al., Crystal structure of oxoboratogermanate NdxSmyEuzGd4-x-y-zGe2B6O34, RUSS J IN C, 45(11), 2000, pp. 1637-1641
Citations number
6
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
45
Issue
11
Year of publication
2000
Pages
1637 - 1641
Database
ISI
SICI code
0036-0236(200011)45:11<1637:CSOON>2.0.ZU;2-C
Abstract
The complex oxide Nd3.33Sm3.71EU3.33Gd3.6Ge2B6O34 belongs to the trigonal s ystem: space group P3(1), a = 9.810 Angstrom, c = 25.847 Angstrom, Z = 3, V = 2154.1 Angstrom (3), rho (calc)=6.63 g/cm(3). The distribution of the Nd, Sm, Eu, and Gd atoms over positions in the solid solution was determined. The structural distortions caused by the redistribution of Ln-O bond length s and by changes in coordination numbers were revealed.