Separation of sulfides of tin, lead and arsenic in concentrated chloride solutions

Authors
Kochetkova, NV Toptygina, GM Krenev, VA Evdokimov, VI
Citation
Nv. Kochetkova et al., Separation of sulfides of tin, lead and arsenic in concentrated chloride solutions, RUSS J IN C, 45(11), 2000, pp. 1782-1785
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
45
Issue
11
Year of publication
2000
Pages
1782 - 1785
Database
ISI
SICI code
0036-0236(200011)45:11<1782:SOSOTL>2.0.ZU;2-3
Abstract
Precipitation of tin(IV), lead (II), and arsenic (III) sulfides from hydroc hloric solutions saturated with calcium and sodium chlorides is studied. Ex perimental data on the SnS2, PbS and As2S3 solubilities in concentrated chl oride solutions at 25 degreesC and partial hydrogen sulfide pressure of 1 a tm are obtained. Conditions for the most complete separation of the metal s ulfides in chloride solutions with a low concentration of hydrochloric acid are determined.