There is increasing evidence that phosphorus has been accumulating in the s
urface horizons of agricultural soils to the extent that some soils represe
nt a potential diffuse source of pollution to surface waters. The relations
hips between equilibrium phosphorus concentration at zero sorption (EPCo) o
f soil and a number of soil physicochemical variables were investigated in
the surface layers of arable and grassland agricultural soils sampled from
the Thame catchment, England. Soil EPCo could be predicted from an equation
including soil test (Olsen) P, soil phosphate sorption index (PSI) and org
anic matter content (OM) (R-2 = 0.88; P<0.001) across a range of soil types
and land use. The simple index Olsen P/PSI was found to be a good predicto
r of EPCo (R-2 = 0.77; P<0.001) and readily desorbable (0.02 M KCl extracta
ble) P (R2 = 0.73; P<0.001) across a range of soil types under arable havin
g soil organic matter contents of <10%.