New efficient catalysts for the palladium-catalyzed coupling of alkynes toenynes

Authors
Lucking, U Pfaltz, A
Citation
U. Lucking et A. Pfaltz, New efficient catalysts for the palladium-catalyzed coupling of alkynes toenynes, SYNLETT, (9), 2000, pp. 1261-1264
Citations number
10
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
9
Year of publication
2000
Pages
1261 - 1264
Database
ISI
SICI code
0936-5214(200009):9<1261:NECFTP>2.0.ZU;2-J
Abstract
Palladium complexes with phosphinooxazoline ligands are very efficient cata lysts for the coupling of alkynes to enynes. The catalyst system could be e mployed in solvent-free reactions and provided an efficient means for the r egiocontrol of cross-coupling reactions between mono- and disubstituted alk ynes. Using enantiomerically pure ligands, kinetic resolution of racemic pr opargylic alcohols to optically active enynes was achieved.