One-pot conversion of oximes to N-(tert-butoxycarbonyl) amines with polymethylhydrosiloxane, Pd-C and di-tert-butyl dicarbonate

Citation
S. Chandrasekhar et al., One-pot conversion of oximes to N-(tert-butoxycarbonyl) amines with polymethylhydrosiloxane, Pd-C and di-tert-butyl dicarbonate, SYNLETT, (9), 2000, pp. 1351-1353
Citations number
22
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
9
Year of publication
2000
Pages
1351 - 1353
Database
ISI
SICI code
0936-5214(200009):9<1351:OCOOTN>2.0.ZU;2-U
Abstract
N-(tert-butoxycarbonyl) amines are directly obtained from oximes of aldehyd es and ketones in one-pot when treated with polymethylhydrosiloxane (PMHS) and di-tert-butyl dicarbonate in the presence of catalytic amount of 10% Pd -C for the first time.