Ds. Brown et al., High loading polymer-supported N-methylmorpholine N-oxide; A practically efficient and readily recyclalbe promoter of the Pauson-Khand reaction, SYNLETT, (11), 2000, pp. 1573-1576
A high loading polymer supported amine N-oxide has been prepared and shown
to be a good, practicable, and readily recyclable promoter of the Pauson-Kh
and reaction under mild conditions, generally affording excellent yields of
cyclopentenones. In addition, use of N-phenylsulfonyl oxaziridine as a co-
oxidant allows use of reduced quantities of the readily available parent po
lymer-supported amine without the need for prior oxidation of the resin.