High loading polymer-supported N-methylmorpholine N-oxide; A practically efficient and readily recyclalbe promoter of the Pauson-Khand reaction

Citation
Ds. Brown et al., High loading polymer-supported N-methylmorpholine N-oxide; A practically efficient and readily recyclalbe promoter of the Pauson-Khand reaction, SYNLETT, (11), 2000, pp. 1573-1576
Citations number
39
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
11
Year of publication
2000
Pages
1573 - 1576
Database
ISI
SICI code
0936-5214(200011):11<1573:HLPNNA>2.0.ZU;2-I
Abstract
A high loading polymer supported amine N-oxide has been prepared and shown to be a good, practicable, and readily recyclable promoter of the Pauson-Kh and reaction under mild conditions, generally affording excellent yields of cyclopentenones. In addition, use of N-phenylsulfonyl oxaziridine as a co- oxidant allows use of reduced quantities of the readily available parent po lymer-supported amine without the need for prior oxidation of the resin.