Exploration of radical transannulations inside a cycloundecadienyne

Authors
Aissa, C Dhimane, AL Malacria, M
Citation
C. Aissa et al., Exploration of radical transannulations inside a cycloundecadienyne, SYNLETT, (11), 2000, pp. 1585-1588
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
11
Year of publication
2000
Pages
1585 - 1588
Database
ISI
SICI code
0936-5214(200011):11<1585:EORTIA>2.0.ZU;2-T
Abstract
An eleven-membered macrocyclic bromomethyldimethylsilyl propargylic ether h as been prepared in order to examine the regioselectivity of a transannular radical process. The vinyl radical intermediate appeared to follow exclusi vely a 6-(pi -endo)endo-trig/7-(pi -exo)exo-trig transcyclization course to create a 6,7-bicyclic skeleton.