Iodomethylation of lactones; Application to the synthesis of 1-deoxy-1-iodo-2-uloses

Authors
Bessieres, B Morin, C
Citation
B. Bessieres et C. Morin, Iodomethylation of lactones; Application to the synthesis of 1-deoxy-1-iodo-2-uloses, SYNLETT, (11), 2000, pp. 1691-1693
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
11
Year of publication
2000
Pages
1691 - 1693
Database
ISI
SICI code
0936-5214(200011):11<1691:IOLATT>2.0.ZU;2-K
Abstract
Iodomethyl lithium, when generated from diiodomethane and methyl lithium in toluene, adds to the carbonyl group of lactones; this allows a direct prep aration of 1-deoxy-1-iodo-2-uloses from aldonolactones.