The operational variables of electrokinetic remediation have not been clear
ed yet, because this method is relatively new and is an innovative techniqu
e in the aquifer remediation. In order to investigate the operational varia
bles of the electrokinetic remediation, a mathematical model has been const
ructed based on the physico chemical mass transport process of heavy metals
in pore water of contaminated aquifer. The transport of the heavy metals i
s driven not only by the hydraulic flow due to the injection of the purge w
ater but also by the electromigration due to the application of the electri
c potential gradient. The electric potential between anode and cathode is t
he important operational variable for the electrokinetic remediation. From
the numerical simulations with use of this model it is confirmed that the r
emediation starts from the up stream anode and gradually the heavy metal is
transported to the down stream cathode and drawn out through the purge wat
er.