Organotin adducts with pyrimidinethione: crystal structure of dimethyldi(pyrimidine-2-thiolato)tin(IV) and diphenyldi(pyrimidine-2-thiolato)tin(IV)

Authors
Hadjikakou, SK Demertzis, MA Kubicki, M Kovala-Demertzi, D
Citation
Sk. Hadjikakou et al., Organotin adducts with pyrimidinethione: crystal structure of dimethyldi(pyrimidine-2-thiolato)tin(IV) and diphenyldi(pyrimidine-2-thiolato)tin(IV), APPL ORGAN, 14(11), 2000, pp. 727-734
Citations number
32
Categorie Soggetti
Chemistry
Journal title
APPLIED ORGANOMETALLIC CHEMISTRY
ISSN journal
02682605 → ACNP
Volume
14
Issue
11
Year of publication
2000
Pages
727 - 734
Database
ISI
SICI code
0268-2605(200011)14:11<727:OAWPCS>2.0.ZU;2-V
Abstract
The complexes dimethyldi(pyrimidine-2-thiolato)tin(IV) (1) and diphenyldi(p yrimidine-2-thiolato)tin(IV) (2) have been structurally characterized by me ans of X-ray crystallography, Complex 1 exhibits strong pi-pi stacking inte ractions and adduct 2 is self-assembled via intermolecular hydrogen bonds, C-H-pi and pi-pi stacking interactions. Partial solvolysis occurs in organi c solvents for 1 and 2, Copyright (C) 2000 John Wiley & Sons, Ltd.