The photopyroelectric (PPE) method in a noncontact configuration was propos
ed to study water migration in starch sheets used for biodegradable packagi
ng. A 1-D theoretical model was developed, allowing the study of samples ha
ving a water profile characterized by an arbitrary continuous function. An
experimental setup was designed or this purpose which included the choice o
f excitation source, detection of signals, signal and data processing, and
cells for conditioning the samples. We report here the development of an in
version procedure allowing for the determination of the parameters that inf
luence the PPE signal. This procedure led to the optimization of experiment
al conditions in order to identify the parameters related to the water prof
ile in the sample, and to monitor the dynamics of the process.