The surface modification of powdered tire rubber to increase its adhesion t
o cement paste was studied. The particles were surface-heated with NaOH sat
urated aqueous solutions for 20 min. Scanning electron microscopy (S.E.M.),
water absorption, density, flexural strength, compressive strength, abrasi
on resistance, modulus of elasticity and fracture energy measurements were
performed using test specimens (water/cement ratio = 0.36) containing 10% o
f as-received or 10% of NaOH-treated rubber The results of fracture energy
and flexural and compressive strength show that the addition of rubber part
icles improves the toughness and reduces the porosity of the specimens. Mas
s loss by abrasion (- 1.2 +/- 0.4% for control specimens; - 1.7 +/- 0.4%, u
sing treated rubber and - 4.0 +/- 1.2% using as-received rubber, after 600
cycles) and electron microscopic examination show that the NaOH surface tre
atment enhances the rubber-matrix adhesion. The use of thus treated tire ru
bber particles, as addition, instead of a coarse aggregate, in cement-based
materials is promising for applications such as driveways or in road const
ruction. (C) 2000 Elsevier Science Ltd. All rights reserved.