Synthesis and X-ray analysis of Mn-Mo mixed metal oxide cluster with cubicframework

Authors
Nishikawa, K Kinoshita, I Nishioka, T Isobe, K
Citation
K. Nishikawa et al., Synthesis and X-ray analysis of Mn-Mo mixed metal oxide cluster with cubicframework, CHEM LETT, (11), 2000, pp. 1342-1343
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
11
Year of publication
2000
Pages
1342 - 1343
Database
ISI
SICI code
0366-7022(200011):11<1342:SAXAOM>2.0.ZU;2-J
Abstract
A reaction of the dinuclear oxometalate [(Bu4N)-N-n](2)[Mo2O7] and (tacn)Mn Cl3 (tacn = 1,4,7-triazacyclononane) in water afforded a new cubic type Mn- Mo mixed metal oxide cluster of [{(tacn)Mn}(2)Mo4O16]. 4H(2)O which has a m oderate bleaching ability towards pinacyanol chloride dye.