The quantum-mechanical behavior of charge carriers at the polysilicon/oxide
interface is investigated. It is shown that a dark space depleted of free
carriers is created at the interface as a consequence of the abrupt potenti
al energy barrier, which dominates the polysilicon capacitance and voltage
drop in all regions of operation of modern MOS devices. Quantum-mechanical
effects in polysilicon lead to a reduction in the gate capacitance in the s
ame way as substrate quantization, and to a negative voltage shift, which i
s opposed to the positive shift caused by carrier quantization in the chann
el. Effects on the extraction of device physical parameters such as oxide t
hickness and polysilicon doping are also addressed.