C. Brosseau et al., How do shape anisotropy and spatial orientation of the constituents affectthe permittivity of dielectric heterostructures?, J APPL PHYS, 88(12), 2000, pp. 7278-7288
The study of dielectric heterostructures has been advancing at a rapid pace
. Much of the interest in these materials stems from the fact that their ph
ysical properties can be systematically tuned by variation of the size and
shape of the constituents. Here we report on extensive computer simulations
of the effective permittivity of dielectric periodic (deterministic) heter
ostructures, having monosized hard core inclusions of anisotropic shape (ro
d, ellipsoid) embedded in an otherwise homogeneous and isotropic matrix. Th
e real and imaginary parts of the permittivity, in the quasistatic limit, a
re rigorously evaluated with the use of the PHI3D field calculation package
and the resolution of boundary integral equations. In this article, we sho
w that the effective permittivity has critical properties near a conduction
threshold. The conduction threshold concentration can be significantly mod
ified by the size, shape, and spatial arrangement of the constituents. More
specifically, it obeys a square law dependence as a function of the aspect
ratio, i.e., the ratio of the smaller dimension to the larger dimension in
both the rodlike and ellipsoidal inclusions. The data exhibit a scaling be
havior and can all be collapsed onto a single master curve, indicative of a
remarkable universality in the conductivity property. The critical exponen
ts which determine how the real and imaginary parts of the effective permit
tivity scale with the distance from the conduction threshold are determined
. Our results are compared with the scaling prediction of the standard perc
olation theory for infinite three-dimensional random lattices of insulator-
normal metal composite systems. We also observed that the conduction transi
tion is shifted towards higher concentrations as the angle between the symm
etry axis and the direction of the applied electric field increases. Increa
sing the contrast ratio, between the permittivity and the conductivity of t
he background medium and the inclusions, results in dramatic changes of the
complex effective permittivity, depending on the geometry of the inclusion
s. The scale-dependent properties and the mechanism which govern criticalit
y are related to the actual area of contacts between the inclusions. (C) 20
00 American Institute of Physics. [S0021-8979(00)07723-9].