Nucleation and coarsening during epitaxy on a substrate subject to periodic strain: Spatial ordering and size uniformity

Citation
Tr. Mattsson et H. Metiu, Nucleation and coarsening during epitaxy on a substrate subject to periodic strain: Spatial ordering and size uniformity, J CHEM PHYS, 113(22), 2000, pp. 10323-10332
Citations number
56
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
113
Issue
22
Year of publication
2000
Pages
10323 - 10332
Database
ISI
SICI code
0021-9606(200012)113:22<10323:NACDEO>2.0.ZU;2-8
Abstract
The diffusion constant of an adsorbed atom changes if the surface is under strain. Because of this, it is reasonable to expect that all diffusion-depe ndent phenomena occur differently on a strained surface. Here we study how homogeneous, metal-on-metal epitaxy is modified when it takes place on a (1 00) surface on which we have imposed a periodic inhomogeneous strain field. The periodic field studied here has square symmetry and a period of a hund red lattice sites. The strain is such that an atom diffusing on the surface has a tendency to drift toward the center of the unit cell of the strain f ield. We deposit atoms on this surface, up to a coverage of 0.15 atoms/site ; then we stop deposition and allow the ensemble of islands formed during d eposition to coarsen. If the deposition flux and the temperature of the sur face are chosen properly, the ensemble of islands generated by this procedu re is nearly periodic in space and has a greatly improved island-size unifo rmity. (C) 2000 American Institute of Physics. [S0021-9606(00)01246-0].