Tr. Mattsson et H. Metiu, Nucleation and coarsening during epitaxy on a substrate subject to periodic strain: Spatial ordering and size uniformity, J CHEM PHYS, 113(22), 2000, pp. 10323-10332
The diffusion constant of an adsorbed atom changes if the surface is under
strain. Because of this, it is reasonable to expect that all diffusion-depe
ndent phenomena occur differently on a strained surface. Here we study how
homogeneous, metal-on-metal epitaxy is modified when it takes place on a (1
00) surface on which we have imposed a periodic inhomogeneous strain field.
The periodic field studied here has square symmetry and a period of a hund
red lattice sites. The strain is such that an atom diffusing on the surface
has a tendency to drift toward the center of the unit cell of the strain f
ield. We deposit atoms on this surface, up to a coverage of 0.15 atoms/site
; then we stop deposition and allow the ensemble of islands formed during d
eposition to coarsen. If the deposition flux and the temperature of the sur
face are chosen properly, the ensemble of islands generated by this procedu
re is nearly periodic in space and has a greatly improved island-size unifo
rmity. (C) 2000 American Institute of Physics. [S0021-9606(00)01246-0].