Electrosynthesis and characterisation of nanostructured palladium-polypyrrole composites

Palladium-polypyrrole composite thin films have been synthesised using thre e different bottom-up procedures all comprising the electrochemical synthes is of palladium nanoparticles that are subsequently potentiostatically depo sited or embedded into an electrochemically produced polypyrrole thin film. Transmission electron micrographs of the resulting composites show that th e metallic inclusions have a mean diameter of about 5 nm with a homogeneous size distribution. Experimental evidence is also provided that both the na noparticles and the composite thin films are electroactive. Preliminary res ults on the extendibility of this approach to the electrosynthesis of other metal-polypyrrole materials (namely Ag-PPy composites) are also presented. (C) 2000 Elsevier Science S.A. All rights reserved.