Effects of preparation condition of photoinduced graft filling-polymerizedmembranes on pervaporation performance

Authors
Wenzel, A Yanagishita, H Kitamoto, D Endo, A Haraya, K Nakane, T Hanai, N Matsuda, H Koura, N Kamusewitz, H Paul, D
Citation
A. Wenzel et al., Effects of preparation condition of photoinduced graft filling-polymerizedmembranes on pervaporation performance, J MEMBR SCI, 179(1-2), 2000, pp. 69-77
Citations number
19
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF MEMBRANE SCIENCE
ISSN journal
03767388 → ACNP
Volume
179
Issue
1-2
Year of publication
2000
Pages
69 - 77
Database
ISI
SICI code
0376-7388(20001115)179:1-2<69:EOPCOP>2.0.ZU;2-1
Abstract
Modification of poly(acrylonitrile) membrane was carried out by heterogeneo us photoinduced graft polymerization of methyl acrylate from the vapor phas e. The technique of transmembrane monomer flow has proved to be effective f or filling pores. The effect of preparation conditions like initiator conce ntration, reaction time and monomer concentration on the membrane separatio n was investigated. These graft modified membranes showed benzene permselec tivity for benzene/cyclohexane mixture (50/50, v/v) on pervaporation. (C) 2 000 published by Elsevier Science B.V.