Structural and catalytic properties of sodium and cesium exchanged X and Yzeolites, and germanium-substituted X zeolite

The conversion of isopropanol in a fixed bed flow reactor was used as a tes t reaction for a number of faujasite-type zeolites which were modified in o rder to increase their basicity. Samples included a CsY zeolite with an int act faujasite structure and an exchange degree of nearly 100% prepared by s olid-state ion exchange, a CsNaY obtained from CsY through exchange with aq ueous NaCl solution, a CsNaX obtained from NaX and aqueous CsCl solution, a nd a Na(Ge)X, with Si replaced by Ge. At 623 K, an isopropanol partial pres sure of 5 kPa in He, and a total feed flow of 90 ml/min, a catalyst mass of 50 mg, initial yields were as follows: NaY: 62% propene, CsNaY: 78% propen e, NaCsX: 10% propene, 0.37% acetone, Na(Ge)X: 8% propene, 11% acetone. Con version in the presence of CsY was < 1%. CO2 adsorption and infrared (IR) s pectroscopy were used to probe basicity, and Na(Ge)X was the only sample to form monodentate carbonates upon CO2 adsorption (bands at 1477 and 1428 cm (-1)). Further characterization with X-ray diffraction (XRD), transmission electron microscopy (TEM), thermal analysis, nitrogen sorption, and isoprop anol sorption was necessary to properly interpret catalytic results by iden tifying samples which contained impurities, had blocked pore systems, or de composed partially during activation or reaction. (C) 2000 Elsevier Science B.V. All rights reserved.