Rhodium and palladium complexes from 1,1 ' and 1,2 ferrocenylphosphine as bidentate ligands. Versatile coordination

Authors
Broussier, R Bentabet, E Laly, M Richard, P Kuz'mina, LG Serp, P Wheatley, N Kalck, P Gautheron, B
Citation
R. Broussier et al., Rhodium and palladium complexes from 1,1 ' and 1,2 ferrocenylphosphine as bidentate ligands. Versatile coordination, J ORGMET CH, 613(1), 2000, pp. 77-85
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
613
Issue
1
Year of publication
2000
Pages
77 - 85
Database
ISI
SICI code
0022-328X(20001027)613:1<77:RAPCF1>2.0.ZU;2-N
Abstract
The complexation of the mixed bidentate ligands 1-diphenylphosphino-1'-diph enylthiophosphinoferrocenyl and 1,2-bis(diphenylphosphino)ferrocenyl with r hodium(I) and palladium(II) species yield a range of mono- and dirhodium or palladium complexes. Their interest as possible catalysts for alkene hydro formylation and alkoxycarbonylation and Heck coupling reactions has been as sessed. Fe[C5Me4P(S)Ph-2][C5Me4PPh2]PdCl2 and Fe[C5H2-1,2-(PPh2)(2)-4-'Bul [C5H5]PdCl2 have been characterized by single-crystal X-ray diffraction stu dies. (C) 2000 Elsevier Science B.V. All rights reserved.