The cyclopermtadienylaluminium etheralkoxide derivative [(eta(1)-C5H5)(2)Al(mu-OCH2CH2O-Pr-n)](2); synthesis and structure

Authors
Szumacher, S Madura, I Zachara, J Kunicki, AR
Citation
S. Szumacher et al., The cyclopermtadienylaluminium etheralkoxide derivative [(eta(1)-C5H5)(2)Al(mu-OCH2CH2O-Pr-n)](2); synthesis and structure, J ORGMET CH, 613(1), 2000, pp. 119-123
Citations number
30
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
613
Issue
1
Year of publication
2000
Pages
119 - 123
Database
ISI
SICI code
0022-328X(20001027)613:1<119:TCED[>2.0.ZU;2-0
Abstract
The reaction of [Cl2Al(mu -OCH2CH2O-Pr-n)](2) (1) with NaCp leads to the fo rmation of etheralkoxy bridged dimer [(eta (1)-C5H5)(2)Al(mu -OCH2CH2O-Pr-n )](2) (2) containing five-coordinate aluminium atoms. The compound was char acterised by H-1-,C-13- and Al-27-NMR spectra and its crystal structure was determined by single crystal X-ray diffraction studies. (C) 2000 Elsevier Science B.V. All rights reserved.