Sulfur(IV) compounds as ligands Part XXV. Halfsandwich ruthenium thiosulfonato complexes. Crystal and molecular structure of [CpRu(dppe){SSO2(4-C6H4Cl)}]

Authors
El-khateeb, M Wolfsberger, B Schenk, WA
Citation
M. El-khateeb et al., Sulfur(IV) compounds as ligands Part XXV. Halfsandwich ruthenium thiosulfonato complexes. Crystal and molecular structure of [CpRu(dppe){SSO2(4-C6H4Cl)}], J ORGMET CH, 612(1-2), 2000, pp. 14-17
Citations number
35
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
612
Issue
1-2
Year of publication
2000
Pages
14 - 17
Database
ISI
SICI code
0022-328X(20001020)612:1-2<14:SCALPX>2.0.ZU;2-C
Abstract
Reaction of the hydrogen sulfide complexes [CpRu(P-P)(SH)] (P-P = dppm (1), dppe (2)) with sulfonyl chlorides RSO2Cl at - 70 degreesC in THF gave the ruthenium thiosulfonato complexes [CpRu(P-P)(SSO2R)] (P-P = dppm (3), dppe (4), R = Me (a), Ph (b), 4-C6H4Cl (c), 4-C6H4NO2 (d)). The structure of 4c was determined by X-ray crystallography. Important molecular geometry data are: Ru-S(I) 239.3(2), S(1)-S(2) 203.2(2), S(2)-O(1) 145.0(5), S(2)-O(2) 14 4.1(5) pm; Ru-S(1)-S(2) 104.23(8)degrees. (C) 2000 Published by Elsevier Sc ience B.V. All rights reserved.