A novel magnetohydrodynamic experiment: Step-rotation of a nematic subjectto a magnetic field

Citation
Cj. Dunn et al., A novel magnetohydrodynamic experiment: Step-rotation of a nematic subjectto a magnetic field, J PHYS CH B, 104(47), 2000, pp. 10989-11000
Citations number
24
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY B
ISSN journal
15206106 → ACNP
Volume
104
Issue
47
Year of publication
2000
Pages
10989 - 11000
Database
ISI
SICI code
1520-6106(20001130)104:47<10989:ANMESO>2.0.ZU;2-S
Abstract
We have studied the time-dependent behavior of the director following the s tep-rotation of a nematic sample subject to a static magnetic field. The di rector orientation has been monitored using ESR spectroscopy, and we have d eveloped a model-independent analysis of the spectra to yield the distribut ion function for the director with respect to the magnetic field. This reve als that immediately following the step-rotation the director is uniformly aligned parallel to the field and then adopts a range of orientations befor e returning to a state of uniform alignment with the director at the step-r otation angle to the field. This unusual behavior of the director is compar ed with the predictions of nematodynamic theory by employing an exact treat ment of the Leslie-Ericksen equations to calculate the time and space depen dence of the director orientation.