Circular dichroism studies of formation of complexes of oxovanadium(IV), cobalt(II) and nickel(II) with (+)-6-aminopenicillanic acid in aqueous solution
N. Ahmad et al., Circular dichroism studies of formation of complexes of oxovanadium(IV), cobalt(II) and nickel(II) with (+)-6-aminopenicillanic acid in aqueous solution, J CHEM S P, 21(2), 1999, pp. 91-97
The complex forming ability of (+)-6-aminopenicillanic acid with oxovanadiu
m(IV), cobalt(II) and nickel(II) in aqueous solution maintained at 35 degre
esC is studied through circular dichroism spectra In these systems, complex
ation is indicated with the development of well defined CD bands in crystal
field region between 18,349-24, 691 cm(-1). The optimum conditions of pH,
stoichiometry, time for attaining maximum complexation and formation consta
nts are reported for these complex ions. The CD bands are assigned to elect
ronic transitions.