A new polymer-attached reagent for the oxidation of primary and secondary alcohols

Authors
Sourkouni-Argirusi, G Kirschning, A
Citation
G. Sourkouni-argirusi et A. Kirschning, A new polymer-attached reagent for the oxidation of primary and secondary alcohols, ORG LETT, 2(24), 2000, pp. 3781-3784
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
24
Year of publication
2000
Pages
3781 - 3784
Database
ISI
SICI code
1523-7060(20001130)2:24<3781:ANPRFT>2.0.ZU;2-5
Abstract
[GRAPHICS] A new, polymer-bound reagent system for the efficient oxidation of primary alcohols to aldehydes and secondary alcohols to ketones in the presence of a catalytic amount of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO) is desc ribed. In most cases, workup of this heavy metal-free oxidation is achieved by simple filtration followed by removal of the solvent. In selected examp les this reagent was compared with the known polymer-bound permanganate and chromium(VI) reagents.