G. Sourkouni-argirusi et A. Kirschning, A new polymer-attached reagent for the oxidation of primary and secondary alcohols, ORG LETT, 2(24), 2000, pp. 3781-3784
[GRAPHICS]
A new, polymer-bound reagent system for the efficient oxidation of primary
alcohols to aldehydes and secondary alcohols to ketones in the presence of
a catalytic amount of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO) is desc
ribed. In most cases, workup of this heavy metal-free oxidation is achieved
by simple filtration followed by removal of the solvent. In selected examp
les this reagent was compared with the known polymer-bound permanganate and
chromium(VI) reagents.