1,2-thiaborolide: A new heteroaromatic pi-ligand containing boron and sulfur

Citation
Aj. Ashe et al., 1,2-thiaborolide: A new heteroaromatic pi-ligand containing boron and sulfur, ORGANOMETAL, 19(24), 2000, pp. 4935-4937
Citations number
43
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
24
Year of publication
2000
Pages
4935 - 4937
Database
ISI
SICI code
0276-7333(20001127)19:24<4935:1ANHPC>2.0.ZU;2-#
Abstract
The heteroaromatic anion lithium 2-(diisopropylamino)-1,2-thiaborolide (3) has been prepared by a synthesis using the Grubbs ring-closing metathesis. 3 has been converted to the Cp*Ru complex 10, the Cp*ZrCl2 complex 11, and the Me2Si-bridged CpZrCl2 complex 15.