Why is the DNA denaturation transition first order?

Citation
Y. Kafri et al., Why is the DNA denaturation transition first order?, PHYS REV L, 85(23), 2000, pp. 4988-4991
Citations number
21
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
85
Issue
23
Year of publication
2000
Pages
4988 - 4991
Database
ISI
SICI code
0031-9007(200012)85:23<4988:WITDDT>2.0.ZU;2-0
Abstract
We study a model for the denaturation transition of DNA in which the molecu les are considered as being composed of a sequence of alternating bound seg ments and denaturated loops. We take into account the excluded-volume inter actions between denaturated loops and the rest of the chain by exploiting r ecent results on scaling properties of polymer networks of arbitrary topolo gy. The phase transition is found to be first order in d = 2 dimensions and above, in agreement with experiments and at variance with previous theoret ical results, in which only excluded-volume interactions within denaturated loops were taken into account. Our results agree with recent numerical sim ulations.