T. Enoki et al., Frustrations in polymer conformation in gels and their minimization through molecular imprinting, PHYS REV L, 85(23), 2000, pp. 5000-5003
We report an experimental realization of a gel system in which frustrations
exist and can be minimized, thus meeting two crucial criteria predicted to
enable memory of conformations in polymers. The gels consist of a thermose
nsitive major monomer component and two minor components. One minor compone
nt is positively charged and will form complexes around negatively charged
target molecules placed in solution. The complexes can be imprinted into th
e gel by then cross-linking the second minor component, which will form cro
ss-links additional to those in the major polymer matrix. The complexes are
destroyed and reformed upon swelling and reshrinking of the gels, showing
that memorization has been achieved.