Natural rubber is widely used in most parts of the world and a significant
amount becomes post-consumer waste. Although it has its traditional uses, t
he waste is mostly either not utilised or under utilised. Thus in search of
better utilisation of the waste, such as using pyrolysis to form liquid pr
oducts, the locally available waste natural rubber has been physically char
acterised and its thermal behaviour investigated by thermogravimetric analy
sis. The present paper describes an attempt to derive the reaction kinetics
for pyrolysis of waste natural rubber in a nitrogen atmosphere at differen
t heating rates in the form of degree of reaction, rate of devolatilisation
, and activation energy. In a comparative study, the physical properties of
some selected biomass wastes locally available in Malaysia are also review
ed.