The paper presents the study of the paramagnetic centers formed by gamma ir
radiation of polycrystaline H2SeO3 and D2SeO3 at room temperature. Accordin
g to their EPR parameters and thermal behaviour these centers were attribut
ed to the SeO2- radicals. The electron spin densities in the orbitals of se
lenium and oxygen aroma Mere calculated. The results obtained by us from H2
SeO3 and D2SeO3 in the form of powder; can compare with those literature ef
fected on the monocrystals.