Some considerations on the superfine and spin densities interactions in the SeO2- radical species

Authors
Citation
M. Contineanu, Some considerations on the superfine and spin densities interactions in the SeO2- radical species, REV CHIM, 51(7), 2000, pp. 497-501
Citations number
14
Categorie Soggetti
Chemical Engineering
Journal title
REVISTA DE CHIMIE
ISSN journal
00347752 → ACNP
Volume
51
Issue
7
Year of publication
2000
Pages
497 - 501
Database
ISI
SICI code
0034-7752(200007)51:7<497:SCOTSA>2.0.ZU;2-L
Abstract
The paper presents the study of the paramagnetic centers formed by gamma ir radiation of polycrystaline H2SeO3 and D2SeO3 at room temperature. Accordin g to their EPR parameters and thermal behaviour these centers were attribut ed to the SeO2- radicals. The electron spin densities in the orbitals of se lenium and oxygen aroma Mere calculated. The results obtained by us from H2 SeO3 and D2SeO3 in the form of powder; can compare with those literature ef fected on the monocrystals.