A SYNTHETIC APPROACH TOWARDS PINAKENE, A C28H14 FRAGMENT OF [70]-FULLERENE

Authors
MEHTA G PANDA G YADAV RD RAVIKUMAR K
Citation
G. Mehta et al., A SYNTHETIC APPROACH TOWARDS PINAKENE, A C28H14 FRAGMENT OF [70]-FULLERENE, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 36(4), 1997, pp. 301-302
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry → ACNP
ISSN journal
03764699
Volume
36
Issue
4
Year of publication
1997
Pages
301 - 302
Database
ISI
SICI code
0376-4699(1997)36:4<301:ASATPA>2.0.ZU;2-K
Abstract
During a projected synthesis of 4,7,11,14-tetramethyldibenzo [fg,op] n aphthacene 3 en route to Pinakene 2, a [70]-fullerene fragment, an unp recedented photochemical reaction leads to dimethylnaphthacene derivat ive 7. Flash vacuum pyrolysis on 7 leads to 8 via a transannular bridg ing.