Ar. Hajipour, RELATIVE STEREOCHEMISTRY OF THE THERMODYNAMIC AND KINETIC ADDITION OFLITHIATED METHYL PHENYL SULFOXIDE TO OXAZIRIDINE, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 36(4), 1997, pp. 329-332
The stereochemical outcome and diastereo selectivity of the thermodyna
mic and kinetic reactions of lithiated methyl phenyl sulfoxide with ox
aziridine is reported. The relative stereochemistry of the major diast
ereomeric products at thermodynamic and kinetic condition has been det
ermined by chemical correlation with the major diastereomeric products
from the reaction of lithiated racemic methyl phenyl sulfoxide with n
itrones.