RELATIVE STEREOCHEMISTRY OF THE THERMODYNAMIC AND KINETIC ADDITION OFLITHIATED METHYL PHENYL SULFOXIDE TO OXAZIRIDINE

Authors
HAJIPOUR AR
Citation
Ar. Hajipour, RELATIVE STEREOCHEMISTRY OF THE THERMODYNAMIC AND KINETIC ADDITION OFLITHIATED METHYL PHENYL SULFOXIDE TO OXAZIRIDINE, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 36(4), 1997, pp. 329-332
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry → ACNP
ISSN journal
03764699
Volume
36
Issue
4
Year of publication
1997
Pages
329 - 332
Database
ISI
SICI code
0376-4699(1997)36:4<329:RSOTTA>2.0.ZU;2-8
Abstract
The stereochemical outcome and diastereo selectivity of the thermodyna mic and kinetic reactions of lithiated methyl phenyl sulfoxide with ox aziridine is reported. The relative stereochemistry of the major diast ereomeric products at thermodynamic and kinetic condition has been det ermined by chemical correlation with the major diastereomeric products from the reaction of lithiated racemic methyl phenyl sulfoxide with n itrones.