THERMOCHEMICAL PARAMETERS OF COMPLEXES OF DI-ISOBUTYLDITHIOCARBAMATE WITH PHOSPHORUS-GROUP ELEMENTS

Authors
DESOUZA AG NETO FD DESOUZA JH MACEDO RO DEOLIVEIRA JBL PINHEIRO CD
Citation
Ag. Desouza et al., THERMOCHEMICAL PARAMETERS OF COMPLEXES OF DI-ISOBUTYLDITHIOCARBAMATE WITH PHOSPHORUS-GROUP ELEMENTS, Journal of thermal analysis, 49(2), 1997, pp. 679-684
Citations number
22
Categorie Soggetti
Chemistry Analytical
Journal title
Journal of thermal analysis → ACNP
ISSN journal
03684466
Volume
49
Issue
2
Year of publication
1997
Pages
679 - 684
Database
ISI
SICI code
0368-4466(1997)49:2<679:TPOCOD>2.0.ZU;2-C
Abstract
The standard molar enthalpy of formation of crystalline di-isobutyldit hiocarbamate complexes of P, As, Sb and Bi(III) has been derived by so lution calorimetry at 298.15 K. The corresponding standard molar entha lpies of sublimation were estimated by means of differential scanning calorimetry. From the standard molar enthalpies of formation of the ga seous chelates the homolytic and heterolytic mean metal-sulphur bond-d issociation enthalpies were calculated.