Viscosities and excess energy of activation for viscous flow for binary mixtures of tetrahydrofuran with 1-butanol, 2-butanol and 1-chlorobutane at 283.15, 298.15 and 313.15 K

Citation
A. Mariano et al., Viscosities and excess energy of activation for viscous flow for binary mixtures of tetrahydrofuran with 1-butanol, 2-butanol and 1-chlorobutane at 283.15, 298.15 and 313.15 K, BRAZ J CH E, 17(4-7), 2000, pp. 459-469
Citations number
14
Categorie Soggetti
Chemical Engineering
Journal title
BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING
ISSN journal
01046632 → ACNP
Volume
17
Issue
4-7
Year of publication
2000
Pages
459 - 469
Database
ISI
SICI code
0104-6632(200012)17:4-7<459:VAEEOA>2.0.ZU;2-B
Abstract
Kinematic viscosities of binary mixtures composed of tetrahydrofuran with l -butanol, 2-butanol and 1-chlorobutane have been measured at 283.15, 298.15 and 313.15 K and atmospheric pressure for the whole range of compositions. The dynamic viscosity, the excess viscosity and the excess energy of activ ation for viscous flow were also calculated. The excess viscosity shows neg ative deviations from ideal behavior for the mixtures tetrahydrofuran with 1-butanol and 2-butanol and a small positive deviation for the binary tetra hydrofuran + 1-chlorobutane system. The experimental results have also been used to test some empirical and semiempirical equations adopted previously to correlate viscosity - composition data.