Syntheses of penta-O-benzyl-myo-inositols, O-beta-L-arabinosyl-(1 -> 2)-sn-myo-inositol, O-alpha-D-galactosyl-(1 -> 3)-sn-myo-inositol, and O-alpha-D-galactosyl-(1 -> 6)-O-alpha-D-galactosyl-(1 -> 3)-sn-myo-inositol

Authors
Koto, S Hirooka, M Yoshida, T Takenaka, K Asai, C Nagamitsu, T Sakuma, H Sakurai, M Masuzawa, S Komiya, M Sato, T Zen, S Yago, K Tomonaga, F
Citation
S. Koto et al., Syntheses of penta-O-benzyl-myo-inositols, O-beta-L-arabinosyl-(1 -> 2)-sn-myo-inositol, O-alpha-D-galactosyl-(1 -> 3)-sn-myo-inositol, and O-alpha-D-galactosyl-(1 -> 6)-O-alpha-D-galactosyl-(1 -> 3)-sn-myo-inositol, B CHEM S J, 73(11), 2000, pp. 2521-2529
Citations number
56
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
ISSN journal
00092673 → ACNP
Volume
73
Issue
11
Year of publication
2000
Pages
2521 - 2529
Database
ISI
SICI code
0009-2673(200011)73:11<2521:SOPO-2>2.0.ZU;2-5
Abstract
Two-step conversions of myo-inositol into (+/-)-2,3,4,5,6- and 1,3,4,5,6-pe nta-0-benzyl-myo-inositols are described. Starting from these monohydroxy d erivatives of myo-inositol, O-beta -L-arabinopyranosyl-(1-->2)-sn-myo-inosi tol from Japanese green tea [], Camellia sinensis, and O-alpha -D-galactopy ranosyl-(1-->3)-sn-myo-inositol (galactinol) as well as its homolog, O-alph a -D-galactopyranosy1-(1-->6(II))-galactinol, were synthesized by way of th e in situ activating glycosylation procedure.(##)