A novel enantiopure proline-derived triazacyclononane: synthesis, structure and application of its manganese complex

Authors
Bolm, C Meyer, N Raabe, G Weyhermuller, T Bothe, E
Citation
C. Bolm et al., A novel enantiopure proline-derived triazacyclononane: synthesis, structure and application of its manganese complex, CHEM COMMUN, (24), 2000, pp. 2435-2436
Citations number
36
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
24
Year of publication
2000
Pages
2435 - 2436
Database
ISI
SICI code
1359-7345(2000):24<2435:ANEPTS>2.0.ZU;2-T
Abstract
The X-ray crystal structure and electrochemical data of a manganese complex [L2Mn2III(mu -O)(mu -AcO)(2)][PF6](2) with L being an enantiopure C-3-symm etric 1,4,7-triazacyclononane derived from L-proline are compared to those of [Me-3- TACN(2)Mn(2)(III)(mu -O)(mu -AcO)(2)][PF6](2); catalytic studies reveal the applicability of the complex in enantioselective epoxidations.