Unexpected dimerisation of a 2H-azaphosphirene complex

Citation
R. Streubel et al., Unexpected dimerisation of a 2H-azaphosphirene complex, CHEM COMMUN, (24), 2000, pp. 2453-2454
Citations number
21
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
24
Year of publication
2000
Pages
2453 - 2454
Database
ISI
SICI code
1359-7345(2000):24<2453:UDOA2C>2.0.ZU;2-Y
Abstract
Heating a 2H-azaphosphirene complex in the solid state afforded the first h ead-to-tail dimer, a 2,5-dihydro-2,5-diphosphapyrimidine complex, a eta (1) -diphosphene complex and another complex having low-coordinated phosphorus centers; whereas the latter was detected only by P-31 NMR spectroscopy, the dimer was isolated and structurally characterized.