Heating a 2H-azaphosphirene complex in the solid state afforded the first h
ead-to-tail dimer, a 2,5-dihydro-2,5-diphosphapyrimidine complex, a eta (1)
-diphosphene complex and another complex having low-coordinated phosphorus
centers; whereas the latter was detected only by P-31 NMR spectroscopy, the
dimer was isolated and structurally characterized.