[Pt-2(GaCp*)(2)(mu(2)-GaCp*)(3)]: structure and bonding situation of the first homoleptic platinum complex with terminal and bridging Cp*Ga ligands

Authors
Weiss, D Winter, M Fischer, RA Yu, C Wichmann, K Frenking, G
Citation
D. Weiss et al., [Pt-2(GaCp*)(2)(mu(2)-GaCp*)(3)]: structure and bonding situation of the first homoleptic platinum complex with terminal and bridging Cp*Ga ligands, CHEM COMMUN, (24), 2000, pp. 2495-2496
Citations number
40
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
24
Year of publication
2000
Pages
2495 - 2496
Database
ISI
SICI code
1359-7345(2000):24<2495:[SABSO>2.0.ZU;2-S
Abstract
A new homoleptic diplatinum complex [Pt-2(GaCp*)(2)(mu (2)-GaCp*)(3)] (Cp* = pentamethylcyclopentadienyl) exhibiting a central unit of two platinum at oms coordinated by five Cp*Ga groups acting as terminal as well as bridging ligands, was synthesized by the reaction of tris(ethylene)platinum(0) with an excess of (Cp*Ga)(6) and was characterized by structural and quantum ch emical methods.