Kv. Parchevsky, A new method for the reconstruction of the particle radius distribution function from the sedimentation curve, CHEM ENGN J, 80(1-3), 2000, pp. 73-79
A new method for the reconstruction of the particle radius distribution fun
ction from the sedimentation curve is proposed. This method permits us to o
btain a continuous smooth distribution function. Two approaches are compare
d. The first approach is based on the calculation of the second derivative
from the sedimentation curve. The second one is based on the solution of th
e original integral equation which describes a sedimentation process. Both
of these approaches can be reduced to the problem of the solution of the Fr
edholm integral equation of the first kind. From the theory of integral equ
ations, it is known that this problem is ill-posed. The usual methods lead
to unstable solutions and we are forced to use special regularizing algorit
hms. In this paper, the Tikhonov regularization method is used to stabilize
the solution of the integral equation. It is shown that the accuracy of bo
th methods is higher than the accuracy of the graphical method, but the app
roach based on the solution of the original integral equation gives a more
stable solution than that based on the derivative. The accuracy of the new
method permits us to reconstruct the fine structure of the particle radius
distribution function. Such an analysis cannot be carried out with the roug
h bar diagram obtained from the graphical method. The new method is absolut
ely indispensable in technology for controlling the degree of powder finene
ss. (C) 2000 Elsevier Science B.V. All rights reserved.