Application of integral encounter theory to account for the spin effects in radical reactions I. Delta g and spin relaxation effects on recombinationkinetics of free radicals

Authors
Gorelik, EV Lukzen, NN Sagdeev, RZ Steiner, UE
Citation
Ev. Gorelik et al., Application of integral encounter theory to account for the spin effects in radical reactions I. Delta g and spin relaxation effects on recombinationkinetics of free radicals, CHEM PHYS, 262(2-3), 2000, pp. 303-323
Citations number
53
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS
ISSN journal
03010104 → ACNP
Volume
262
Issue
2-3
Year of publication
2000
Pages
303 - 323
Database
ISI
SICI code
0301-0104(200012)262:2-3<303:AOIETT>2.0.ZU;2-8
Abstract
Integral encounter theory is applied to investigate spin effects in radical recombination. Effects of electron spin relaxation and of S/T-0 mixing by an external magnetic field are considered. An analytical expression for the stationary rate constant is obtained from which appropriate conditions for experimental investigations are predicted. (C) 2000 Elsevier Science B.V. All rights reserved.