Structures that should be described in higher-symmetry, centrosymmetric space groups. Part 1. The disordered structures of [(CH3CH2)(4)N](3){[(SCH2CH2S)MoS3](2)Fe}, [(CH3CH2)(4)N](2){[S2CN(C2H5)(2)](4)Fe4S4} and [(CH3CH2)(4)N](3){[(SCH2CH2S)MoS3](2)Fe}center dot 1/4CH(3)CN, and the ordered structure of [(CH3CH2)(4)N](3)-{[(CH3)(2)NCS2Cu](2)MoS4}center dot 2CH(3)CN

Authors
Citation
Ns. Weng et Sz. Hu, Structures that should be described in higher-symmetry, centrosymmetric space groups. Part 1. The disordered structures of [(CH3CH2)(4)N](3){[(SCH2CH2S)MoS3](2)Fe}, [(CH3CH2)(4)N](2){[S2CN(C2H5)(2)](4)Fe4S4} and [(CH3CH2)(4)N](3){[(SCH2CH2S)MoS3](2)Fe}center dot 1/4CH(3)CN, and the ordered structure of [(CH3CH2)(4)N](3)-{[(CH3)(2)NCS2Cu](2)MoS4}center dot 2CH(3)CN, CHIN J ST C, 19(6), 2000, pp. 405-410
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN journal
02545861 → ACNP
Volume
19
Issue
6
Year of publication
2000
Pages
405 - 410
Database
ISI
SICI code
0254-5861(200011)19:6<405:STSBDI>2.0.ZU;2-K
Abstract
The space groups of [(CH3CH2)(4)N](3) {[(SCH2CH2S)MoS3](2)Fe} and [(CH3CH2) (4)N](2) {[S2CN(C2H5)(2)](4)Fe4S4} are revised from Cc to C2/c by solving t he C2/c structure from the structure factors that are calculated from the C c structure. The structures are both disordered in one of the tetraethylamm onium cations. The space group of [(CH3CH2)(4)N](3) {[(SCH2CH2S)MoS3](2)Fe} .1/4CH(3)CN is revised from Pc to P2(1)/c; because of the severe disorder i n the cations that was not addressed in the original refinements, only the atomic coordinates of the metal-cluster anions could be revised. The space group of [(CH3CH2)(4)N](3) {[(CH3)(2)NCS2Cu](2)MOS4}. 2CH(3)CN (originally described in P (1) over bar) is re-assigned to C2/c. The general descriptio ns of the structures are unchanged in the higher-symmetry settings. The rev ised coordinates are given.