Structures that should be described in higher-symmetry, centrosymmetric space groups. Part 1. The disordered structures of [(CH3CH2)(4)N](3){[(SCH2CH2S)MoS3](2)Fe}, [(CH3CH2)(4)N](2){[S2CN(C2H5)(2)](4)Fe4S4} and [(CH3CH2)(4)N](3){[(SCH2CH2S)MoS3](2)Fe}center dot 1/4CH(3)CN, and the ordered structure of [(CH3CH2)(4)N](3)-{[(CH3)(2)NCS2Cu](2)MoS4}center dot 2CH(3)CN
Ns. Weng et Sz. Hu, Structures that should be described in higher-symmetry, centrosymmetric space groups. Part 1. The disordered structures of [(CH3CH2)(4)N](3){[(SCH2CH2S)MoS3](2)Fe}, [(CH3CH2)(4)N](2){[S2CN(C2H5)(2)](4)Fe4S4} and [(CH3CH2)(4)N](3){[(SCH2CH2S)MoS3](2)Fe}center dot 1/4CH(3)CN, and the ordered structure of [(CH3CH2)(4)N](3)-{[(CH3)(2)NCS2Cu](2)MoS4}center dot 2CH(3)CN, CHIN J ST C, 19(6), 2000, pp. 405-410
The space groups of [(CH3CH2)(4)N](3) {[(SCH2CH2S)MoS3](2)Fe} and [(CH3CH2)
(4)N](2) {[S2CN(C2H5)(2)](4)Fe4S4} are revised from Cc to C2/c by solving t
he C2/c structure from the structure factors that are calculated from the C
c structure. The structures are both disordered in one of the tetraethylamm
onium cations. The space group of [(CH3CH2)(4)N](3) {[(SCH2CH2S)MoS3](2)Fe}
.1/4CH(3)CN is revised from Pc to P2(1)/c; because of the severe disorder i
n the cations that was not addressed in the original refinements, only the
atomic coordinates of the metal-cluster anions could be revised. The space
group of [(CH3CH2)(4)N](3) {[(CH3)(2)NCS2Cu](2)MOS4}. 2CH(3)CN (originally
described in P (1) over bar) is re-assigned to C2/c. The general descriptio
ns of the structures are unchanged in the higher-symmetry settings. The rev
ised coordinates are given.