Pressure and temperature variation of the depolarized light scattering spectra of the fragile glass-former liquid salol

Citation
G. Pratesi et al., Pressure and temperature variation of the depolarized light scattering spectra of the fragile glass-former liquid salol, EUR PHY J B, 18(2), 2000, pp. 283-287
Citations number
20
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
EUROPEAN PHYSICAL JOURNAL B
ISSN journal
14346028 → ACNP
Volume
18
Issue
2
Year of publication
2000
Pages
283 - 287
Database
ISI
SICI code
1434-6028(200011)18:2<283:PATVOT>2.0.ZU;2-2
Abstract
The pressure and temperature dependences of the depolarized light scatterin g spectra of salol have been measured at isobaric condition P = 1 bar for T between 328 and 393 K, and at isothermal condition T = 343 K for P between 1 and 625 bar, i.e. outside the metastable liquid region. The experimental results for both the alpha- and beta -relaxations can be well described by the Mode Coupling Theory. The independence of the power-law parameters alp ha, and consequently b and gamma, from the thermodynamic variables T and P is demonstrated. The critical temperature T-c at 1 bar and the critical pre ssure P-c at T = 343 K have been determined from the normal liquid state.