Vapor-liquid equilibria for the ternary system benzene plus n-heptane plusN,N-dimethylformamide at 101.33 kPa

Authors
Blanco, B Sanz, MT Beltran, S Cabezas, JL Coca, J
Citation
B. Blanco et al., Vapor-liquid equilibria for the ternary system benzene plus n-heptane plusN,N-dimethylformamide at 101.33 kPa, FLU PH EQUI, 175(1-2), 2000, pp. 117-124
Citations number
21
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
FLUID PHASE EQUILIBRIA
ISSN journal
03783812 → ACNP
Volume
175
Issue
1-2
Year of publication
2000
Pages
117 - 124
Database
ISI
SICI code
0378-3812(20001101)175:1-2<117:VEFTTS>2.0.ZU;2-Y
Abstract
Isobaric vapor-liquid-equilibrium (VLE) data at 101.33 kPa for the system f ormed by benzene, n-heptane and N,N-dimethylformamide (DMF) are reported. D ata reduction has been carried out through Wilson, NRTL, and UNIQUAC thermo dynamic models for correlating the liquid-phase activity coefficients. Acti vity coefficients of the components in the mixture indicate positive deviat ions from Raoult's law. Experimental results show that DMF is a good extrac tive solvent that reverses the volatility of the binary system benzene + n- heptane. (C) 2000 Elsevier Science B.V. All rights reserved.