M. Frigoli et al., Photomodulable materials. Synthesis and properties of photochromic 3H-naphtho[2,1-b]pyrans linked to thiophene units via an acetylenic junction, HELV CHIM A, 83(11), 2000, pp. 3043-3052
The synthesis of 3H-naphtho[2,1-b]pyrans linked to mono-, di-, or terthioph
ene via an acetylenic junction is described (Schemes 2 and 3). The syntheti
c approaches involve successive Sonogashira coupling reactions. The photoch
romic properties in solution of these novel materials were investigated und
er continuous irradiation.